Monday, November 25, 2019

Compared to the original Daniell Cell Essay Example

Compared to the original Daniell Cell Essay Example Compared to the original Daniell Cell Paper Compared to the original Daniell Cell Paper By completing and testing this hypothesis our group believes that it will factor in the aim of increasing the voltage and current of our Daniell Cell. Hypothesis 2 According to the Standard Reduction Potentials for Half-Reactions table, our group hypothesises that by changing the half cells so that their E0 values are a greater distance apart that the voltage and current will show an increase and improve the Daniell Cell. The general make up of a Daniell Cell is two half cells, one with copper metal (Cu) and the other cell using zinc metal (Zn). The electrolyte then is both sulfates of each metal, CuSO4 and ZnSO4 making up the Cell. According to the Standard Reduction Potentials for Half-Reductions (SRPHR), Copper and Zinc is a good pair since Copper is a fairly strong oxidizing agent and Zinc is a very good reducing agent which gives a high voltage between these two half cells. Corrosion Doctors, 2006 The group has decided in changing one of these half cells to a better oxidizing agent or a reducing agent the voltage of our cell will increase and therefore support our hypothesis. Since this is a school experiment, it is very hard to access the best oxidizing agents, which has left us with Potassium Permanganate (KMnO4) as our best oxidizer and magnesium (Mg2+) as our best reducing agent. When both ionic concentrations (the electrolyte) are at 1M and the room temperature is at 25oC you can calculate the voltage of what two half cells would be by using the given E0 value. Copper has an E0 of +0. 34 volt and Zinc has an E0 of -0. 76 volt and you subtract the oxidizer from the reducing agent which gives 1. 10 V (volts). The calculations for the magnesium and potassium permanganate are as follows, potassium permanganate E0 value is 1. 52 and the magnesium E0 value is -2. 37 which gives 3. 89 volts. Under these conditions the voltage should increase from 1. 10 volts to 3. 89 volts, in which will support our second hypothesis. Hypothesis 3 After extensive research into different forms of salt bridges, our group believes that in using the porous pot salt bridge the decrease in resistance provided by the pot will increase the voltage and current readings of the original Daniell Cell. A salt bridge, in chemistry, is a device used to connect the oxidation and reduction half-cells of an electrochemical cell. It is also apart of the internal circuit of the cell with the external circuit being the wire that connects the anode to the cathode. Salt bridges usually comes in two types: glass tube and filter paper with other portable options still available. One type of salt bridges consists of U-shaped glass tubes filled with a relatively inert electrolyte, usually potassium nitrate. The conductivity of the glass tube bridges depends mostly on the concentration of the electrolyte solution. The other type of salt bridges consists of a filter paper, also soaked with a relatively inert electrolyte, usually potassium nitrate because it is chemically inert. Conductivity of this kind of salt bridges depends on a number of factors: the concentration of the electrolyte solution, the texture of the filter paper and the absorbing ability of the filter paper. Generally smoother texture and higher absorbency equates to higher conductivity. A porous pot or other porous barrier between the two half-cells may be used instead of a salt bridge; they give a much higher current flow since the resistance is much less which is ideal for this investigation. Chemistry Virtual Textbook, 2006 In the Daniell Cell the porous pot cell consists of a central zinc anode dipping into a porous pot containing the zinc sulfate solution. The porous pot is, in turn, immersed in a solution of copper sulfate contained in a large beaker, which acts as the cells cathode. The use of a porous barrier prevents the copper ions in the copper sulfate solution from reaching the zinc anode and undergoing reduction. This would render the cell ineffective by bringing the battery to equilibrium. Our group has hypothesised that using the Porous Pot as the salt bridge will bring upon an increase in voltage and current therefore making a Better Battery. Balanced Chemical Equations and E0 values Zn2+ (aq) + 2e- Zn(s) E0 = -0. 76 V Cu2+ (aq) + 2e- Cu(s) E0 = 0. 34 V Zn(s) Zn2+ (aq) + 2e- Cu2+ (aq) + 2e- Cu(s). Zn(s) + Cu2+ (aq) Zn2+ (aq) + Cu(s) E0C = E0ox + E0red = 0. 76 + 0. 34 E0C = 1. 10 V Mg2+ (aq) + 2e- Mg(s) E0 = -2. 37 V Cu2+ (aq) + 2e- Cu(s) E0 = 0. 34 V Mg(s) Mg2+ (aq) + 2e- Cu2+ (aq) + 2e- Cu(s) Mg(s) + Cu2+ (aq) Mg2+ (aq) + Cu(s) E0C = E0ox + E0red = 2. 37 + 0. 34 E0C = 2. 71 V 5 Mg2+ (aq) + 10e- 5 Mg(s) E0 = -2. 37 V 2 MnO4- (aq) + 16 H+ + 10e- 2 Mn2+ + 8 H20 (l) E0 = 1. 52 5 Mg(s) 5 Mg2+ (aq) + 10e- 2 MnO4- (aq) + 16 H+ + 10e- 2 Mn2+ + 8 H20 (l) 5 Mg(s) + 2 MnO4-(aq) + 16 H+ 5 Mg2+ (aq) + 2 Mn2+ + 8H2O (l) E0C = E0ox + E0red= 2. 37 + 1. 52 E0C = 3. 89 Method Daniell Cell 1. Using two beakers place them close together and fill the beakers half way with the chosen electrolytes. 2. Place the Copper and Zinc metals in their respective salt solutions which are both 0. 1 M in concentration 3. Connect the wires to each electrode (metal) and connect the wires though a voltmeter/ammeter 4. Saturate the salt bridge (filter paper) with Potassium Nitrate and insert each end into both half-cell solutions. 5. Record Results for both current and voltage Hypothesis One 1. Setup the original Daniell Cell 2. After setting up and functioning the original Daniell Cell, change the concentration of the CuSO4 solution to 0. 5M. 3. Record the results shown on the voltmeter and ammeter 4. After this, change the concentration of the CuSO4 solution to 1M 5. Record the results shown on the voltmeter and ammeter. 6. Repeat this with the zinc half cell, by changing the copper half cell back to 0. 1M and increasing the zinc sulfate to 0. 5M then 1M. 7. Record the results of the voltage and current for these two experiments. Hypothesis Two (A) 1. Place two beakers side by side, filling them up half way with MgSO4 0. 1M and CuSO4 0. 1M. 2. Place the metals in their respective salts (sulfate solutions) 3. Connect the wires to each metal and plug the ends into the ammeter/voltmeter. 4. Now that the external circuit is present, saturate the salt bridge (in this case, filter paper) with Potassium Nitrate (KNO3) solution and place into each half cell. 5. Turn on the voltmeter/ammeter and record results. Hypothesis Two (B) 1. Place two beakers side by side, filling them up half way with MgSO4 0. 1M and MnO4 0. 02M 2. Place the magnesium metal in its respective salt 3. Place an inert metal such as carbon in the MnSO4 solution 4. Connect the wires to each metal and plug the ends into the ammeter/voltmeter 5. Now that the external circuit is present, saturate the salt bridge (in this case, filter paper) with Potassium Nitrate (KNO3) solution and place into each half cell. 6. Turn on the voltmeter/ammeter and record results. Hypothesis Three 1. Using a larger beaker, fill with the Cathode (Copper) electrolyte to around 1/2 full 2. Place the Porous Pot (which has been soaked in KNO3) in to the beaker and pour the other electrolyte (Zinc) inside. 3. Add the two electrodes to their distinguished salts. 4. Turn on the ammeter/voltmeter and record the results. Super Cell 1. Repeat steps 1, 2 and 3 in hypothesis three. 2. Instead of using Copper and Zinc half cells, use MnO4 (Potassium Permanganate) and MgSO4 (Magnesium) with MgSO4 being the anode. 3. The concentrations for each half cells are as follows; KMnO4 0. 02M and MgSO4 0. 1M 4. Use an ammeter/voltmeter to receive the final data for the investigation. Results Tables Hypothesis One: In reference to the Nernst Equation and Le Chi telier principle, our group believes that by having increased concentration in the cathode and a reduced concentration in the anode in each electrolyte will cause the voltage and current readings to increase and improve the Daniell Cell. Voltage (V) Trial ZnSO4 0. 1M Avg % Dif ZnSO4 0. 5M Avg % Dif ZnSO4 1M Avg % Dif CuSO4 0. 1M 0. 98 0. 95 0. 99 0. 97 0. 97 0. 98 0. 97 0. 97 0 0. 96 0. 97 0. 96 0. 96 -1. 03 CuSO4 0. 5M 1. 05 1. 02 1. 04 1. 04 7. 22 Â  CuSO4 1M 1. 15 1. 09 1. 10 1. 11 14. 4 Current (mA) Trial ZnSO4 0. 1M Avg % Dif ZnSO4 0. 5M Avg % Dif ZnSO4 1M Avg % Dif CuSO4 0. 1M 0. 20 0. 22 0. 25 0. 22 0. 22 0. 22 0. 24 0. 22 0 0. 21 0. 23 0. 26 0. 23 4. 55 CuSO4 0. 5M 0. 33 0. 44 0. 38 0. 37 68. 2 CuSO4 1M 0. 45 0. 56 0. 49 0. 50 127 Hypothesis Two: According to the Standard Reduction Potentials for Half-Reactions table, our group hypothesises that by changing the half cells so that their E0 values are a greater distance apart that the voltage and current will show an increase and improve the Daniell Cell. Voltage (V) Trial Zn(s) | Zn2+(aq) Avg % Dif Mg(s) | Mg2+(aq) Avg % Dif Cu(s) | Cu2+(aq) 0. 98 0. 95 0. 99 0. 97 1. 71 1. 82 1. 75 1. 76 83. 33 MnO4- | Mn2+ 2. 76 2. 86 2. 89 2. 84 192. 78 Current (mA) Trial Zn(s) | Zn2+(aq) Avg % Dif Mg(s) | Mg2+(aq) Avg % Dif Cu(s) | Cu2+(aq) 0. 20 0. 22 0. 25 0. 22 0. 32 0. 35 0. 34 0. 34 54. 54 MnO4- | Mn2+ 0. 59 0. 55 0. 58 0. 57 159. 1 Hypothesis Three: After extensive research into different forms of salt bridges, our group believes that in using the porous pot salt bridge the decrease in resistance provided by the pot will increase the voltage and current readings of the original Daniell Cell. Trial Voltage Avg % Dif Current Avg/ % Dif Daniell Cell 0. 98 0. 95 0. 99 0. 97 0. 20 0. 22 0. 25 0. 22 Porous Pot 1. 07 1. 08 1. 09 1. 08 11. 34 27 28 25 27 12172 Safety During the investigation the group used five different types of electrolytes for the extent of the experiment. These five solutions were Zinc Sulfate, Copper Sulfate, Potassium Nitrate, Potassium Permanganate and Magnesium Sulfate. These five solutions yielded the property that meant they could be dissolved into water with Zinc, Potassium and Magnesium all forming a clear colour. Copper Sulfate forms a blue solution, whereas Potassium Permanganate forms a dark purple solution. Throughout the duration of the investigation students must wear safety glasses along with a lab coat to protect their skin from any contact with the solutions. Keep the experimental area clear of books and other items that may cause an incidence of spilling or breaking equipment. In an emergency situation, such as contact with the eyes and skin, the patient must flush and wash away the solution for fifteen minutes and remove all contaminated clothing. If large amounts of any of these solutions are ingested do not induce vomiting and call for a physician immediately. Conclusion and Discussion In relation to the first hypothesis the results have supported what has been stated. From an in depth study of both the Nernst and Le Chatelier principles the hypothesis was made that by changing the concentration in the cathode and keeping the anode at its lowest concentration will show an increase in current compared to the original Daniell Cell. The average of the Daniell Cells voltage and current was 0. 97 volts and 0.22 mA, then the concentration in the cathode and anode were increased and decreased giving positive results. When our hypothesis was tested the current, as expected, increased vastly going from an average of 0. 22 0. 50 mA by just changing the concentration. As well as the current the voltage also increased slightly going from 0. 97 1. 11 volts. This can be explained by using Ohms Law which is: which can be said as; when increasing I (current) as long as the resistance stays the same the voltage is also going to increase. The second hypothesis was once again supported by encouraging results. In this case both the cathode and anode were getting changed at different times in hoping finding two half cells that gave the best voltage reading. The anode was changed first and by doing this the group achieved an improved reading, to complete the hypothesis the cathode was then changed which meant the new battery was using the two half cells that were the furthest away from each other that could be obtained in classroom conditions. The Daniell Cells starting voltage was 0. 97 volts and when using Carbon + KMnO4 0. 02M as the cathode and Copper + CuSO4 0. 1M as the anode the reading we received was 2. 84 V which was a much better results to the original Cell. Le Chateliers Principle can be used to explain the decrease in voltage (compared to the redox table) in the results involving these two half cells. Since the concentration in the cathode is lower in contrast to the anode the shift in equilibrium is towards the anode which then causes less of the solution used giving a lower voltage. The current was increased by 159. 1 % which then can be clarified by Ohms Law which says that when increasing voltage the current will also increase when the resistance is kept at a constant. The third and final hypothesis was in relation to the changing of the salt bridge which was hoping to bring about a change in the current flow. The group only tested one other type of salt bridge due to time constraints which proved very effective. The porous pot was a new type of salt bridge which caused the internal circuit to be much more efficient and also make the battery portable. The current reading given by using the porous pot salt bridge was far better then the group expected, going from 0. 22 mA 27 mA (12172 % increase) which was a very pleasing result firmly supporting our hypothesis. The voltage also showed an improvement of over 11 % which shows strong support again to our hypothesis. Therefore our Super Cell was able to be formed by observing these result tables. Since the aim of this investigation was to find the best battery with the most current and voltage these changes must be made. The two half cells have to be as far away as possible on the redox table to cause the highest E0 value or voltage. The salt bridge that must be used is the porous pot as it provides a very high current reading and causes the battery to be more realistic as it will be portable. The last change is that the cathode must have the highest concentration for an extra increase in current. This factor was not testable for our super cell as the only concentration for the MnO4 was 0. 02 M Our Super Cell is then as follows Mg(s) + MgSO4 (0. 1M) MnO4 (0. 02M) + C(s) Using Porous Pot soaked in KNO3 Voltage = 3. 0740. 001 V (216. 91% difference) Current = 1191 mA (53,990% difference) These results show the vast improvement of the new Super Cell compared to the original Daniell Cell. The aim has therefore been attended to and completed and all three hypotheses have been supported with compatible results. Evaluation Although the results received were very positive and back up all hypotheses there were many limitations and errors that could have been taken care of in the future. The external circuits or the wires connecting each half cell almost all had rust on them which acts as a resistance causing a reduced voltage and current. The rust was also not consistent on each set of wires, which meant when the group used different wires the voltage and current readings differed each time. The volt and ammeters were very inaccurate at times and most of the time not giving a current reading which meant there was less time to carefully finish each experiment which then caused more inaccuracy in the results. Another error which occurred due to equipment, which was unfortunately unavoidable, was each of the solutions used. After each reading was taken we were to pour the solutions back into their containers. The solutions may have been contaminated whilst the cell was operating and as the solution was then poured back into the original container the contamination spread. This would eventually decrease the concentration of electrolyte and as such change the data, decreasing the voltage and current. To fix this error, the solutions should not be poured back into the containers again. Another error was the lack of trials within the experiment. Due to time constraints we complete the desired number of trials for each hypothesis. It is desirable to have as many tests as possible, one trial to establish the basis while the others are trying to be as accurate as possible. By not having a complete number of trials we limited the results that have been found. If we were able to complete more trials, we would have been able to have a fairer and more accurate result. We would be able to overcome this by having a longer time to conduct our trials. This would have given more time to be more precise with the work that was completed. A different filter paper salt bridge should have been used each time testing, since when used once the paper soaks up the electrolytes of each half cell which becomes inexact next time its put into use. The filter paper also dries out after a while which reduces the current of the cell, making the experiment more inaccurate as time progresses. The group was only provided with 0. 02 M KMnO4 which then forced us to not put one of our hypotheses into use in creating our Super Cell which was having the concentration in the anode lower then the concentration in the cathode. Another error was the use of Carbon as the inert metal in the KMnO4 solution. Since Carbon is not completely inert the current was unable to flow, free of resistance from the Carbon, therefore reducing the current reading of the cell. The magnesium metal was also an issue as it tends to oxidise instantly with oxygen causing an oxide layer on the metal and also reducing the current reading of the cell. Further investigation could possibly be to test many other hypotheses such as the surface area of the metals to make our results more thorough. More electrodes could have been added to the half-cells. This would create a cell with a larger surface area in which the reactions would take place. This would then allow a larger current and voltage as there would have been more electrons to create a higher current. There would have been a larger amount of area in which the electrons would be able to be taken from. The larger the surface area, more electrons are able to be attracted to the electrode, consequently producing more voltage and current. Russian Chemical Views, 2009 Cutting edge battery research and development have allowed improvements such as changing the metals in the half cell to still make it more efficient eg. Lithium. Lithium-ion batteries are incredibly popular these days. Theyre so common because, pound for pound, theyre some of the most energetic rechargeable batteries available. Lithium batteries are disposable batteries that have lithium metal or lithium compounds as an anode. The term lithium battery comprises of many types of cathodes and electrolytes. The most common type of lithium cell used in consumer applications uses metallic lithium as anode and manganese dioxide as cathode, with a salt of lithium dissolved in an organic solvent. (Brain, 2008) Improvements such as the electrodes being further apart in the redox table, eg lithium and silver would have been able to create a higher voltage. Again this is a problem because it is very unsafe as lithium is so reactive that it will react with the oxygen in the air. Therefore it may not be possible to create a Daniell Cell out of those materials. Further research into looking into ways of creating more reactive yet stable electrodes we could create a cell which supports the claims of the Redox table but is also able to be completed within a class room environment. Bibliography All about electrochemistry. Chemistry Virtual Textbook. 2006 Chemistry 1. (Feb. 2009. ) chem1. com/acad/webtext/elchem/Figure 1: Chemistry Pictures. Daniell Cell. 2006 Electrochemistry Principles. (Feb. 2009. ) chemistrypictures. org/d/175-2/electrochemistry. jpg Electrochemical Cell. 2006 Corrosion Doctors. (Feb. 2009. ) http://corrosion-doctors. org/Electrochem/Cell. htm Electrochemical Cells. Online Resource Centre. 2004 Oxford University. (Feb. 2009. ) http://hyperphysics. phyastr. gsu. edu/hbase/chemical/electrochem. html#c2 Electrochemical Determination of Surface Area of Metals. IOP Electronic Journals. 2009. Russian Chemical Views. Mar. 2009. iop. org/EJ/abstract/0036-021X/47/5/R02 Electrochemical Reactions. Electrochemistry. 2007 Bodner Research Web. (Feb. 2009. ) http://chemed. chem. purdue. edu/genchem/topicreview/bp/ch20/electro. php Figure 2: How voltage and current relate? 2005 Ohms Law. All about circuits. (Feb. 2009. ) allaboutcircuits. com/vol_1/chpt_2/1. html LE CHATELIERS PRINCIPLE. Concentration Equilibrium. 2003 Chemistry Guide. (Feb. 2009. ) chemguide. co. uk/physical/equilibria/lechatelier. html Lower, Stephen. The Nernst Equation. All about Electrochemistry. 2005. Chemistry 1. Feb. 2009. chem1. com/acad/webtext/elchem/ec4. html Nernst Equation. Electric Work. Science Waterloo. 2008 (Feb. 2009. ) science. uwaterloo. ca/~cchieh/cact/c123/nernsteq. html Figure 3: The Nernst Equation. Hermann Walther Nernst. 2004 Biol-Paisley. (Feb. 2009. ) biol. paisley. ac. uk/marco/enzyme_electrode/Chapter2/Nernst. htm Voltage and Current. Electrochemistry. 2004 Hyper chemistry. (Feb. 2009. ) chemlin. net/chemistry/electrochemistry. htm

Thursday, November 21, 2019

Boss Personal Statement Example | Topics and Well Written Essays - 500 words

Boss - Personal Statement Example Although management and leadership are not utterly different, the two concepts may not be the same either. There are many ways in which management differs from leadership, especially when looking at the differences from leadership skills and management skills. Leadership emphasizes more on vision of the project than implementation. On the contrary, management entirely focuses on implementation and vision is second guessed. Further, leadership takes a keen interest in situation dynamics; these dynamics provides the leadership with hints on the right action to take. Leadership makes attempts that alter the culture in order to attain the best results that benefit the majority. On the contrary, management focuses on techniques and it does not advocate for changes. Rather, management strives to maintain the status quo and order in an organization, as well adapt to the traditions. Furthermore, leadership focuses on risk taking and positive possibilities while management worries so much of the negative consequences, which might result from an action. Finally, leadership aims to rebuild and reshape an organization to ensure that the organization moves towards the vision and objectives. It does this through the employment of persuasion skills, as well as possibility ideas. These actions do not take any consideration of the position of the organization. On the other hand, management focuses on achieving the prescribed organization and it adopts attitudes and behavior according to position or level. Management does not disclose information and knowledge to workers; they fear that their own position might be compromised by information leakage. There are many characteristics of good leaders, which can take time and space to discuss. However, the scope of this paper does not allow me to discuss the entire characteristics that good leaders should have. Therefore, I will discuss a few key qualities, which describes a good leader. Good leaders are

Wednesday, November 20, 2019

Microsoft Monopoly Essay Example | Topics and Well Written Essays - 500 words

Microsoft Monopoly - Essay Example The reasons that lead to Microsoft being reconnoitered for antitrust performance is the fact that there were reports of Microsoft Company abusing the position they had as one of the leaders in supplying operating systems of computers. It leads to various lawmakers carrying out investigations if Microsoft Company was creating a monopoly to the markets available for the computer software’s. These lawmakers later found out that Microsoft Company was causing a monopoly in the industry of computers.The lawmakers came out with facts used in supporting their judgments (McLaughlin, 1999). Microsoft Company created Microsoft office which gave services to everyone in any professional field. The Microsoft office was to be used to operate an operating system that was specifically from Microsoft Company. This operating system used by Microsoft, is windows. McLaughlin(1999) affirms that during the internet development, Microsoft Company tried to put measurements that were to eradicate and p ush out other companies competing with them in terms of net browsing. By doing so, Microsoft Company came up with the internet explorer which was to be used freely in their all operating systems introduced. The introduction of internet explorer came when people were spending their money in using Netscape Navigator and other browsers. According to the lawmakers, Microsoft Company was mortified of these exclusive dealings. This type of regulation gives Microsoft sole rights to a particular commodity.

Monday, November 18, 2019

Retail Park Assignment Example | Topics and Well Written Essays - 2750 words

Retail Park - Assignment Example Major business brands would be attracted to a retail park thus giving consumers a much wider range to choose from. A retail park can also use brown field sites, if they are small. The use of a brown field sites would mean that acquiring of land, residences and other structures for building of the retail park would not have to be done. And also new land would not have to be acquired for the building of roads and railways as the ones already could be renovated and used. Since Medway does have problems associated with low wages, a retail park would create innumerable job opportunities for the people of Medway. Also, retail parks would provide opportunity for unskilled and low-skilled people to earn, thus addressing Medway's problem of lack of skills in certain areas. Having a retail park will lead to developments in social and economical infrastructure. This in turn will increase Medway Town Council's revenue. Thus the area surrounding the retail park will develop, and more people will come and settle in the area. First the demand for labor increases as shown by then rightward shift of the curve DI. Thus the wage rate increases from W to W1. Next the supply of labor increases in response to higher wages and a new supply curve marked S2 shifts on to the right. Ultimately the equilibrium wage rate is established at W2.However the serenity of the sub-urban country side of Medway could be lost due to the setting up of a retail park. Thus there is likely to be opposition from the environment conscious local communities. Preserving the country side should be of high priority. Due to the increase of traffic and the development of commercial infrastructure such as airports and offices there would be sound and air pollution. The Medway council would have to think of a way of disposing waste products from the retail park (Needham, 2006). These waste products could flow to the rivers and canals in the vicinity thus giving rise to water pollution. Certain species of birds and animals endemic to this area could be driven away as a result of acquiring land to set up the retail park. This could lead to protests from environmentalists. One of the major economic effects of the proposed retail park would be on the local shopping centers in Medway. The first major issue of an out-of-town retail development is the loss of business by the local shopkeepers. Acquiring land and the demolition of existing buildings would mean that the Medway council would have to pay compensation to the property owners and relocate them. The Medway council would have to bear this cost. Money will have to come from banks at high interest rates for this purpose. In order to have ample parking space, a large area of land would has to be rented. This will cost a considerable amount. Scenario A-2 Medway, which is located 30 miles East of London and 40 miles North West of Dover, is one of the largest

Friday, November 15, 2019

Human Resource Management at McDonalds

Human Resource Management at McDonalds Human resource management is the basis of all management activity, but it is not the basis of all business activity. The basis of management is always the same: getting the people of the business to make things happen in a productive way, so that the business prospers and the people thrive. Torrington et al (2005:4) Human Resource can be say to be the strategic and coherent approach management of an organisations most valued assets. The people working these individually and collectively contribute to the achievement of the objectives of the business. Human resource is one of the important parts of any organisation management in the 21st century and up still date. Any corporate firm can get competitor advantage by human resource. The term Human resources can be viewed in two contrasting ways. Placing emphasis on the word Human implies that an organisations assets are valuable human beings with feelings and aspirations that should be respected and nurtured. Highlighting the word resource may have the effect of devaluing the human element by relegating people to a mere resource that is to be deployed as effectively and efficiently as possible, like a piece of machinery. These associated have been embodied as soft and hard HRM (storey, 1992). Soft HRM is often associated with quality-enhancing and value-adding measures, whereas hard HRM is linked to cost-cutting and cost minimization strategies (Schuler and Jackson, 1987). Importance of Strategic Human Resource Management Strategy human resource management is very important because it help to resolve the problems that affect people management programs in the organisation. In every organisation, the employee and customers are very important and the try to listen to their employee and resolve whatever complains from them or the customer. This will help to increase the performance of the organisation. Strategy human resource management also help to improve a business performance and foster an environment of innovation and flexibility among employees. Strategy human resource management help about assessing the companys internal strength and weakness. This is very important as the strengths and weaknesses of the companys human resources have a direct effect on the future of the company. It also helps to check whether the expectations of the employee are addressed properly. The management of Strategy human resource management try to provide the right strategy that will enable the employee to work in a very safe environment and make sure those employees expectation are look into one after the other. Strategy human resource management help to develop the maintainer of competency among workers and it also help to motivate workers to perform their job properly and increase productions. From the above we can see that strategic human resource is now coming to play a very important role in todays business word. Strategy human resource management is all about strategically managing a businesss human resource in a manner that works to the overall benefit of the business. Strategy human resources deal with organisational performance and systems of practice and human resources management deal with an individual employee performance. The role of strategy human resources management or human resources management is to establish a system of human resources management practices that transforms middling work performance to human assets and sustaining the heightened work motivation, expanded job opportunities, and unique skill, knowledge and abilities. http://www.smallbusinessbible.org/strategic_humanr_management.html Comparison of SHRM with HRM The difference between strategy human resources management and human resources management is that strategy human resources management is strategy and human resources management is not, although some resources suggest that strategy human resources management is actually one of the applications of human resources management within an enterprise. The key feature where the two ideas are connected is that they are precisely in approach toward people management. BRIEF HISTORY OF MCDONALDS McDonalds started as a burger brand in 1940 and it was formed by two Brother Richard and Maurice McDonald in San Bernardino, California. It progressed from a hotdog stand into one of the worlds leading restaurant chain. By 1953, McDonalds brothers began franchising their restaurant and the first was taken by Neil Fox who opened in other parts of California. McDonalds Corporation came into existence in 1954 after an entrepreneur and milkshake mixer salesman Ray Kroc acquired the franchise of McDonalds outside California after which he bought the business rights from the McDonalds brothers for $2.7 million in 1961. By 1974 the first restaurant in the UK opened and 1988, they had opened in the communist country in Belgrade, Yugoslavia later in Moscow, China and India. In 2003, the Im loving it campaign was launched and by 2005, McDonalds started a Mc Delivery service in Singapore. McDonalds has been looking for a growth strategy for a very long time. And their foreign operation amount for more than half the companys revenue. McDonald has over 30,000 restaurants over 100 countries in the world today. And they maintain the top position in the fast food industry for the past 50 years. Amongst the award bagged by McDonalds is the Catalyst award for its program for fostering leadership development in women and McDonalds has been backing the summer Olympics since 1984. Business strategy of McDonalds in the UK Employment planning: McDonalds try to make the right plans in employing the right number of staffs that the organisation need at the right time. This is the process by which the organisation attempt to ensure that it has the right number of qualified people in the right place and at the right time. Selection: McDonalds involves in choosing from the available candidates the individual predicted to be most likely to perform successfully in the job. They select but the skills and unskilled individual and try to train them in other to make them understand the objective of the organisation. Selection is not always the best process of employing staffs in the organisation because skills will be lack. Training: McDonalds also used the training strategy to improve and develop the skills of the workers in the organisation. Although training is very important in most organisation but its better to bring the right people with the right skill and then give them the right training so they will understand better and know the objective of the training. Education: The management of McDonald provide education for some staffs that are really willing to retain in the organisation. This education is to improve their performance and to give them more ideas about the economic and how the business is operating. Performance: The Company always chose a right time to check the performance of their workers. The performance of the worker can help the company to make the right changes at the right time and the right department of the workers. These has help MacDonald to build a better services. Pay: Macdonald is a big restaurant with so many branches around the world and helps to reduce the unemployment around us. The Company give a good pay to their staffs and encourage them to work. Staff retention: Macdonald tries to keep their staffs and give them promotions to enable them become a manager of a branch someday in the future. Staff retention is very important to most organisations. This will help the staffs to know what really is happening within the organisation and try to suggest a best opinion to fight that out. Contribution of Strategy Human Resource in McDonald Staffing- McDonald should try to get people with the appropriate skills, knowledge, abilities, and experience to fulfil the organisation objectives. Rewards McDonald need to give reward to the staffs who work very hard in development of the organisation. Employee development- the organisation should also help in developing the staffs through providing training and knowledge for them in other to perform a good job. Employee maintenance- maintaining staffs is important in the development of the company. The administration is should try to encourage the staff and reward them in the good job done. Many organisations try to establish why people leave by conducting exit interviews but these are rarely sufficiently accurate, as many people will not give the full reason why they are leaving for fear of jeopardising future reference requirement or because they may wish to return to the organisation at some later stage. There organisation should make sure they try to maintain and look after their staff in other to keep them happy. Employee relation McDonald should develop the relationship between the staffs and the management in other to bring up a smiling environment within the work place. CONCLUSION McDonalds is seen as a global restaurant offering a range of products in a highly competitive and fragmented market. The company must positively respond to both internal and external issues to avoid losing sales and market share. They have been able to achieve a broad scope of business activity as they adopt the cost leadership strategy. There offer food prepared in the same high quality manner worldwide, tasty and reasonable priced delivered in a consistent low key and friendly environment. The opportunities and threats present in the environment enables managers to look both internally and externally to direct their strategy from the information given as it allows them to know their weakness and guard against them as well as make use of opportunities available to them. SHRM NEW MANAGER IN MCDONALDS As the manager of McDonalds, the percentage of highly skilled labour/ talent recruitment will be increase, but low skilled will be reduce as they are the ones directly involved in preparing food and serving customers. Human resource strategy in McDonalds encourage employee involvement and engagement to improve customer service but recruitment and selection in McDonalds is of little emphasis as the nature of the job is mechanical hence most of their recruits are fast learners who can learn on the job rather quickly. There is a rare case of training and development of staff as they are low skilled and the need for the need for developing them would not be beneficial to the corporation. The strategy of McDonalds is based on concept of Michael Porters differentiation and low- cost leadership as their products are mass produced and cost can be reduced by doing this, the threat this can cause is that its competitors like Burger King and KFC can also mass produce at a low cost. Differentiation can be described as marketing technique used by a McDonalds to establish strong identity in the restaurant business. It can also be called segmentation strategy. In McDonalds, there is a huge number of unskilled labours whose employment contact are mostly on short term basis, hence the need for a huge pension budget will not be necessary, this will be seen as an opportunity for the corporation to save revenue. Also in areas of training and development, since they train on the job and there is no series of further training carried out, the corporation does not lose skill and revenue when such employees decide to terminate their employment. (McDonalds Strategic Human Resources Management available at http://www.scribd.com/doc/26247206/Mcdonald-s-Strategic-Human-Resource.

Wednesday, November 13, 2019

Statues of David Essay -- essays research papers

There have been many staues of David sculpted by famous artists like Donatello, Verrocchio, and Michelangelo. Bernini’s version of David and is about to begin his attack on Goliath, as he appears posing. The statue seems to be moving through space and the action suggests that the action of flinging the stone requires a lot of room around David. The statue forces the observer to look past the actual subject and focus more on the surroundings. He seems to have very muscular legs, and appears to be ready to turn and throw a stone from his sling. This is the most dramatic pose that Bernini could have picked and was chosen because it shows a sudden burst of energy and a moment of suspense as well. Bernini’s David is different from that of other artists because there is an expression of concentration that makes the statue a more imposing piece of artwork.   Ã‚  Ã‚  Ã‚  Ã‚  Donatello’s David was created for the courtyard of the Palazzo Medici. The statue takes on a different pose, and was one of the first free-standing nude statues of the ancient world. l when compared to Bernini’s, it is more classical. Bernini’s rendition is posing and relaxed like a Greek god would be. Donatello made the ancient Greek style popular during this time. Donatello’s David has long flowing hair and has one of his legs placed firmly on top of the head of Goliath, representing his victory over the behemoth. He portrayed David as the slayer of Goliath and as a symbol of the independent republ...

Monday, November 11, 2019

Absolutely True Diary of a Part Time Indian Summary

January 17, 2013 Nicole Samuels The Absolutely True Diary of a Part Time Indian Chapter 1-3 Summary In chapter one, we are introduced to the narrator, Arnold Spirit, nicknamed Junior. He describes himself, as being of lanky build, with an overly large skull, feet and hands. He has a medical condition called Hydrocephalus, which is an excess of fluid in the skull causing swelling of the brain.Junior went through a very risky surgery at the age of 6 months, which would normally kill or permanently damage the brain of the patient, but luckily came out undamaged. Junior has frequent seizures, a lisp and stutter. He matured having 42 teeth and had to get 10 pulled all at once with minimal novocaine. He could only have cheap glasses with big black frames. He lives on the reservation and is the weakest and smallest of them all so is beat up frequently and belongs to â€Å"the Black-Eye-of-the-Month-Club†. He tells us about how he loves to draw, and that it is the only thing he is go od at.Chapter two is where Junior reveals that he is poor, saying that he is â€Å"just a poor-ass reservation kid living with his poor-ass family on the poor-ass Spokane Indian Reservation†. He also gives us the very important math equation of â€Å"Poverty = empty refrigerator + empty stomach†. He tells about how good a piece of KFC chicken tastes after not eating for a long time. He tells us about how he wishes he could blames his parents for their poverty but cant because he loves them too much and they were born into poverty as were their parents, and their parents, and so on and so forth.He talks about how his parents had dreams but didn’t do anything about it, and draws a picture of who his parents could have been if they had followed their dreams. He tells us about how being poor makes you feel, like you’re hopeless. Junior also delves into a painful memory and tells us about the time he heard his father shoot his dog Oscar, who was his best frien d, and could do nothing about it. In the third chapter we are introduced to Juniors best human friend, Rowdy. Rough, mean, rude, and willing to beat up anything and anyone, Rowdy watches out for Junior.Rowdy convinces Junior to go the Spokane tribe’s annual Labor Day celebration, the Powwow. While there Junior angers Rowdy and Rowdy shoves Junior and he runs away, straight into three 30 year old men who beat him up. Rowdy finds him on the ground and vows revenge, and gets it later that night when the men have passed out. He shaves off their eyebrows and cut off their braids, which are a big deal to native men. Junior tells us more about Rowdy, and in his calculations they have spent more than 48,000 hours in each others company.Chapter 9-11 Summary Junior worries that Roger will take revenge for Junior having punched him in the face, wishing Rowdy were still his friend. He asks his grandmother for advice and she tells him it means that roger respects him, but Junior believes she is just crazy. The next day Junior’s parents don’t have enough gas to drive him to school, so he starts the 22 mile trek to school. Along the way junior runs into Eugene, his father’s best friend. Eugene is an alcoholic of the happy sorts, and he gives Junior a ride to school on his motorcycle.When they arrive at school, all the white kids just stare at junior and Eugene, and Roger passes by Junior but doesn’t kick his butt, only says he’ll see him around, and looks impressed. Juniors pretty pumped over this and says Hi to the porcelain beauty Penelope only to be shot down by her, and thinks to himself that he may have impressed the king but the queen still doesn’t approve of him one little bit. In chapter ten Junior tells us the story of Dawn, a beautiful Indian girl with legendary braids who he fell in love with at the age of twelve.Junior had no shot with Dawn, but still confessed to Rowdy his love for her. Rowdy tells Junior that Daw n does not care about him. At all. But Junior still loves her. And so he cries over her, and tells us he is the opposite of a warrior because he is too emotional. He asks Rowdy to keep everything a secret, and Rowdy does. It is Halloween in chapter 11, and Junior goes to school in the simplest and cheapest costume he can think of, a homeless man, because he already has the wardrobe for it.Penelope goes a homeless woman, saying it is a political statement against the treatment of homeless people in the USA, and is going trick-or-treating for spare change to donate to the homeless. Junior says he is making a statement against the treatment of homeless Native Indians in the USA, and will also go trick-or-treating for spare change, and maybe they cold donate together. Miraculously Penelope agrees. Later that night, while trick-or-treating, Junior is jumped by three guys in Frankenstein masks who kick him, spit on him and take the money for charity.Junior wonders if one of the guys was R owdy. The next day Junior tells Penelope what happened, and she is horrified and tells him she will put his name on her donation anyway. Junior thinks that after this Penelope and he will get closer, but of course this doesn’t happen. You do not become popular overnight. Junior wishes he could go to Rowdy for advice to get Penelope to like him, but already knows Rowdy would say â€Å"The first thing you have to do is change the way you look, the way you talk, and the way you walk. And then she'll think you're her fricking Prince Charming†

Friday, November 8, 2019

buy custom American Culture during the 1820 and 1830s essay

buy custom American Culture during the 1820 and 1830s essay In the 1820s and the 1830s, America faced the era of democracy and era of eradicating slavery. During this period, America experienced the niche of democracy and there it involved national politics. In terms of democracy, the most prominent thing that was being addressed was the issue of slavery and the way it could be abolished from the system (Holt, 1983). Artists like Harriet Beecher Stowe advocated for a non-slavery culture; she wrote about the accounts of abolitionists and slavery in her book Uncle Toms cabin. This brought about the abolitionist transformation. In 1831, William Lloyd Garrison started publishing The Liberator, an abolitionist newspaper dedicated to equality for all Americans including the African Americans (CliffsNotes). There was radical abolition movement that was meant to eradicate slavery. Many historians were included in this era that included Robert Abzug, Richard Blackett, Aileen Kraditor among others. These fellows brought about the changing culture of America accepting African Americans as equal, and tried to eradicate slavery (Green, 2009). In this time, there also emerged a movement called Young American Movement, which was led by Stephen Douglas. The movement was meant to embrace and enhance commerce, technology, and internationalism. Through the combination of these two facts, the America became a great success. This culture brought about the Lincoln- Douglas debates. Lincoln said that the US could not be divided more to success as a half slave and half-free state (Johannsen, 1965). This would not bring up the economic success that the country needed. In this era, the need for democracy emerged, an activity termed as American Renaissance came to existence. It involved usage of newspapers, magazines, and communication articles to portray democracy. This was tested by poets like Whitman and Emily Dickinson; they used unrhymed and off rhyme verses to portray their messages. Most of the themes that they put on their articles were for slave liberation and economic enhancements. Buy custom American Culture during the 1820 and 1830s essay

Wednesday, November 6, 2019

Jon D, Rockefeller essays

Jon D, Rockefeller essays John D. Rockefeller created the empire of Standard Oil. His firm grasp of business and his determination to do whatever it took to succeed and be the king of oil propelled him to great heights. But how did he get to the top? After Rockefeller left his job as a bookkeeper in 1859 to seek his own fortune, he joined forces with an Englishman named Marcie Clark. They formed a business as merchants in grain, hay, meat, and other goods. Taking advantage of the extra business that the war gave them, the firm flourished . In four short years, the Clark and Rockefeller Co. made great profits. However, our young John wasn't willing to sit back and relax in just one prosperous venture, the oil business was calling him. Rebates were given as a bonus for giving the railroads big business.{ "The published rates were charged to smaller independent businesses and a lower unpublished rate was charged to big suppliers."} In addition to this price break, the big firms were also given part of the higher prices charged to the smaller companies. Through this, smaller businesses were driven out of the market because they couldn't make as much profit as the larger companies. The strength of Rockefeller's business was in his ability to overpower any competition. He was bigger, stronger, and wealthier than anyone he came in competition with, he could simply starve them out of business. His success was due to the fact that he had a tremendous desire for achievement and the skills to take him there. He was a master of the business that he ran. He chose the best managers, saved money by being efficient in every area of operation and took any necessary steps to control the market. His plants and his company were simply the biggest and the best. By 1900, Standard Oil was in near complete control of the oil industry, controlling 90% of the United States total oil output. This success came at others expense though, and it was catch...

Monday, November 4, 2019

Land Use Element in San Marcos Research Paper Example | Topics and Well Written Essays - 500 words

Land Use Element in San Marcos - Research Paper Example Long term goals influence short term goals for example, in the private investment or specific plans. There are many advantages of this plan of San Marcos in that land use has considered the type of location. San Marcos location is a proximity away from good neighborhoods. Land use will ensure economic growth as San Marcos will have inhabitants who will conduct business or promote one. In addition, with new inhabitants so does need of education creep in, making San Marco an educational hub. However, this close proximity to a lot of neighborhoods enhnaces lack of privacy and a high population which comes with competition of resources. San Marcos modern areas are full of natural habitat like wildlife, agriculture and vernal pools. This is advantageous in that the sigh provides aesthetic relief, attracts rainfall and is thus encouraged and maintained. The main significant reason for leaving an open space and conservation are in san Marcos is that it makes it easy for individuals living there to identify the natural habitat, historical background of the area and the culture of the people. San Marco’s suburbs are intentionally packed with open space which has natural habitat. This is to set aside the rich and mighty from the rest of the town giving them the needed privacy. Moreover, the open space ensures a high quality of air away from polluted air of the cities. Open space and conservation will enhance the quality of living by staring with the air that residents breathe whci is qu;laity air. Its aesthetic beauty is also amazing Convesresely, even though the space is good for air and beauty open space widens the gap between the rich and the poor. This further drives the peole in different ways thus lack of unity. San Marco housing strives to deliver secure, but cheap housing for the community.

Friday, November 1, 2019

Entomology Essay Example | Topics and Well Written Essays - 750 words - 2

Entomology - Essay Example Dietary assessment has become an integral part of clinical evaluation and nursing assessment. Good nutrition is not only important for preventing disease, but also for comprehensive management of a sick patient. In this essay, I plan to reflect on the food I consumed over the previous week and compare with US guidelines for dietary consumption. Dietary assessment includes 24 hour recall of food intake of each day of the week, including the type and quantity, calories analysis, estimation of protein, fat and other important nutrients like vitamins and minerals and comparing with standard references for respective age, sex and physiological condition like pregnancy, lactation and adolescence. This is then averaged to per day analysis. One week's recall of food may not be the best guide for nutrition assessment. However, it keeps matter simple for calorie calculation. From my previous week food recall, it is evident that total calorie intake on an average is about 2500 kcal per day, in excess of my requirement. The recommended calorie requirement for my age and sex is about 1900 calories. The protein intake is about 25 grams when I need about 45 grams. Total fat is about 30% (when it should be less than 20%) and mainly constituting saturated fat and dietary fibre is only about 10% (when it should be 30%). Except for some iron and calcium in the breakfast and some vitamins in the snacks, my diet is poor in vitamins and minerals. Also, there is increased consumption of non milk extrinsic sugars in the form of coke and cookies. The diet does not contain fresh fruits or vegetables or starchy staple foods. Nor does the diet contain any milk. Of course, the amount of alcohol is in moderation. Due to the excess calorie intake and predominance of saturated fats and sugary foods, Ana is at risk of chronic diseases like obesity, cardiovascular disease, hypertension, arthritis and chronic pulmonary disease. Consumption of acidic foods and non milk extrinsic sugars (like in c oke, pastries, chocolates) are cariogenic and are the beginning of periodontal diseases. Also, diet poor in minerals and vitamins can lead to multi-vitamin deficiencies, anemia and malnutrition. Improper diet can also have a psychological effect leading to depression. It is important for me to refer to the dietary guidelines and alter my diet. First of all, the total calorie value of food should not exceed 2000 k cals. According to the National Food Guide to an adult’s diet, bread, cereals and potatoes should comprise one third of the diet and preferably whole grains. Another one third should comprise of fruits and vegetable